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General Properties of Hydrogen


Although hydrogen is present in large quantities, it is rarely found naturally in the free state. It is mostly found in chemical compounds where it binds to other elements. The most common example we can take is water, where hydrogen bonds with an oxygen molecule. When hydrogen burns, it reacts with oxygen in the atmosphere to form water. This is also the primary reason why it is called “Hydrogen”, which derives from the Greek word “hydrogenes” meaning creator of water.
Position of Hydrogen on the Periodic Table
Hydrogen is similar to Alkali metals of group IA and halogens of group VII-A. Therefore, it is at the top of the periodic table.

Similarity with Group IA (Alkali Metals)

1. Both alkali metals and hydrogen have an electron in their valence shell.
Explanation:
Synthesis (Z = 1) – K, 1
Li (Z = 3) – K 2, L 1
Na (Z = 11) – K 2, L 8, M 1
K (Z= 19) – K 2 , L 8 , M 8 , N 1
2. Hydrogen and elements of group IA show the same outer configuration ns 1
Explanation:
H (Z=1) – 1s 1
Li (Z = 3) – 1s 2, 2s 1
Na (Z=11) – 1s 2 , 2s 2 , 2p 6 , 3s1
K (Z= 19) – 1s 2 , 2s 2 , 2p 6 , 3s 2 , 3p 6 , 4s 1
3. Hydrogen also forms halides such as alkali metals.
Explanation:
IA: NaCl, KBr.
Hydrogen: HCl, HI.
4. Hydrogen gas is released at the cathode during electrolysis.
5. The oxidation state of alkali metals and hydrogen is +1.
6. Hydrogen halides undergo ionization in aqueous solution, similar to alkali metal halides.
Explanation:
HCl (sulu) → H + (sulu) + Cl – (sulu)
NaCl (sulu) & # 8594; Na + (sulu) + Cl – (sulu)
7. Hydrogen can also occur in non-metallic compounds such as alkali metals.
Explanation:
Hydrogen: H 2 S

IA Na 2 S

Similarity of Hydrogen to Halogens
1. Both Hydrogen and Halogen are not metals. (iodine excluded due to its partial metallic character)
2. Hydrogen has a higher electronegativity (2.1).
3. Ionization potential is high.
4. A halide ion (X – ) that readily accepts an electron and forms a hydride ion (H –).
5. Both Hydrogen and halogen form compounds with metals and non-metals.
Explanation:
Halogen: HCl (H is not metal)
Hydrogen: H 2 S ( S is not metal)
Therefore, hydrogen is more like halogen than alkali metals. Therefore, the position of hydrogen is not confirmed in the periodic table.

Differences from Alkali Metals and HalogensGeneral Properties of Hydrogen

• Less electropositive than alkali metals and less electronegative than halogens.
• It contains only one proton (but no neutron) in its nucleus and only one electron in the extranuclear part.
• Forms a neutral oxide.
• The sizes of H and H ions are much smaller than those of alkali metals.
• Hydrogen ion (H + ) is unstable in water unlike Na + and K + ions .
Properties of Hydrogen
Physical Properties of Hydrogen
1. Colorless, odorless, neutral gas.
2. Less soluble in water.
3. Extremely flammable.
4. Burns with blue flame.
5. Very low boiling points.

Chemical Properties of Hydrogen

1. Dihydrogen is relatively inert at room temperature due to the strong bond enthalpy of the H – H bond.
2. Atomic hydrogen is produced under a high electric arc.
3. Its orbit is not complete with a single electron.
4. Hydrogen combines with almost every element.
Hydrogen Isotopes
Hydrogen shows three isotopes:
1. protium left( _{1}^{1}H right):(11H ): zero neutrons
2. Deuterium left( _{1}^{2}H right):(12H ): Has a neutron
3. tritium left( _{1}^{3}H right):(13H ): It has two neutrons.
Also Read: Detailed Information on Hydrogen Isotopes

Hydrogen Allotropes

Molecular hydrogen exists in two isomeric forms.
1. Ortho-Hydrogen: In this type, the two proton nuclear spins are aligned in parallel.
2. Para-Hydrogen: In this type, the two proton nuclear spins are aligned antiparallel.
Different Forms of Hydrogen
Atomic Hydrogen:
Molecular hydrogen is produced when it is passed through an electric arc (2273k) striking between tungsten electrodes. The reaction is endothermic and heat is stored in atoms.
H 2 2H- Heat
(Heat at 2273 K in an electric arc)
The liberated hydrogen atoms recombine to form H, with the evolution of a large amount of energy that can be used for welding purposes.
Hydrogen formed:
Hydrogen is hydrogen at the moment it is produced, that is, at the moment it is just released. The resulting hydrogen is much more reactive and is a much stronger reducing agent than ordinary hydrogen.
The reason for the activity of newly formed hydrogen is:
• Atomic state (atom is more reactive than molecules).
• Chemical energy released during the reaction.
• High internal pressure due to formed hydrogen atoms.

Reactions with organic compounds
It reacts with many organic compounds in the presence of catalysts to yield useful hydrogenated products of commercial importance. For example,
• Hydrogenation of vegetable oils in the presence of nickel catalyst.
• Hydroformylation of olefins is converted to aldehyde and then alcohol.

Hydrogen Usage Areas

1. In the preparation of ammonia.
2. As fuel in the preparation of fuel gases such as water gas.
3. As a reducing agent in metallurgy
4. In nuclear fusion, a large amount of energy is released in stars.

References:
https://evrimagaci.org/hidrojen-9846

Writer: Can Baskin


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